研究领域和兴趣:
能量储存及转换材料的设计、合成和表征 化学电源中的电极/电解液界面研究 可移动能源器件的设计及其在3C电子、新能源汽车及规模储能方面的应用 近年本课题方向承担的主要课题:
中关村科技园区重点支持产业领域专项,基于新型能源的LED道路照明示范工程重大产业化项目, 350万元, 2007-2008 北京市科技计划项目,新一代正极材料LiFePO4的产业化技术研究,Z070901310701, 180万元,2007-2008 国家科技部863项目, 改善磷酸铁锂高温性能的关键技术研究, 2006AA03Z229, 89万元, 2007-2008 工信部“电子信息产业发展基金”项目,磷酸铁锂正极材料的研发与产业化,工信部财[2008]192号,400万元,2008-2010。 工信部“电子信息产业发展基金”项目,磷酸铁锂动力电池及系统集成技术研发与产业化,300万元,2009-2011。 国家科技部863重点项目,铁锂正极材料规模化生产和应用关键技术研究,2009AA0352002,2000万元,2010-2012 中关村战略新兴产业化项目:纯电驱动汽车用动力锂电池系统项目,500万元,2012-2014 科技部中新国际合作项目:高能密度锂离子电池电极材料研究,2012DFG52130,92万元,2012-2014 工信部/财政部/科技部---新能源汽车产业技术创新工程,动力电池项目(分别参加天津力神和宁德新能源项目),2012-2015,400万元,正极材料负责人 主要论文:
Mi Y.Y., Gao P., Liu W.*, Zhang W.D., Zhou H.H.*, Carbon Nanotube-loaded Mesoporous LiFe0.6Mn0.4PO4/C Microspheres as High Performance Cathodes for Lithium-ion Batteries. J. Power Sources, 2014, 267:459-468. Lin C.F., Xin Y.L., Cheng F. Q., Lai M.O., Zhou H.H.*, Lu L.*, Recent Development in the Rate Performance of Li4Ti5O12, Applied Science and Convergence Technology, 2014,23 (2):72-77 Wang C., Wan W., Guo H., Zhou H.H. *, Chen J.T.*, Zhang X.X., Huang Y.H.*,Hierarchical MoS2 nanosheet/active carbonfiber cloth as a binder-free and free-standing anode for lithium-ion batteries,Nanoscale, 2014, 6:5351–5358 Wan W., Lee H.S., Yu X.Q.*, Wang C., K. Nam K. W., Yang X.Q.*, Zhou H.H.*, Tuning the electrochemical performances of anthraquinoneorganic cathode materials for Li-ion batteries through the sulfonic sodium functional group , RSC Adv., 2014, 4:19878-19882 Wang C., Su C.,Wan W., Guo H., Zhou H.H., Chen J.T.*, Zhang X.X., Huang Y.H.*,High sulfur loading composite wrapped by 3D nitrogen-doped graphene as a cathode material for lithium–sulfur batteries,J. Mater. Chem. A, 2014,2:5018-5023 Lin C.F., Fan X., Xin Y.L., Cheng F. Q., Lai M.O., Zhou H.H.*, Lu L.*, Li4Ti5O12-based anode materials with low working potentials, high rate capabilities and high cyclability for high-power lithium-ion batteries: synergistic effect of doping, incorporating a conductive phase and reducing particle size,J. Mater. Chem.A,2014,2(26):9982-9993 Lin C.F., Fan X., Xin Y.L., Cheng F. Q., Lai M.O., Zhou H.H.*, Lu L.*, Monodispersed mesoporous Li4Ti5O12 submicrospheres as anode materials for lithium-ion batteries: morphology and electrochemical performances,Nanoscale,2014, DOI: 10.1039/C4NR00960F 李光胤,黄震雷, 张占军*, 周恒辉*,LiNi1/3Co1/3Mn1/3O2低温性能及动力学分析,中国科学?化学,2014,in press. Chen S., Xin Y.L., Zhou Y.Y., Ma Y.R., Zhou H.H.*, Qi L.M.*, Self-supported Li4Ti5O12 nanosheet arrays for lithium ion batteries with excellent rate capability and ultralong cycle life, Energy Environ. Sci., 2014,7(6):1924-1930 Wan W., Wang C., Huang Y.H., Zhang W.D., Chen J.T.*, Zhou H.H.*, Zhang X.X., Excellent performance of nanoscaled Fe3O4 as anode material promoted by mosaicking into porous carbon framework. Func. Mater. Lett., 2014, 7(2): 1450005. Lin C.F., Ding B., Xin Y.L., Cheng F.Q., Lai M.O., Lu L.*, Zhou H.H.*, Advanced electrochemical performance of Li4Ti5O12-based materials for lithium-ion battery: Synergistic effect of doping and compositing, J. Power Sources, 2014, 248: 1034-1041. Cheng F.Q., Xin Y.L., Huang Y.Y., Chen J.T., Zhou H.H.*, Zhang X.X., Enhanced electrochemical performances of 5 V spinel LiMn1.58Ni0.42O4 cathode materials by coating with LiAlO2. J. Power Sources, 2013, 239: 181-188. Cheng F.Q., Chen J.T., Zhou H.H.*, Manthirama A.?, Structural and electrochemical characterization of (NH4)2HPO4-treated lithium-rich layered Li1.2Ni0.2Mn0.6O2 cathodes for lithium-ion batteries, J. Electrochem. Soc., 2013, 160 (10) : A1-A7 Chen S., Wang M., Ye J.F., Cai J.G., Ma Y.R., Zhou H.H.*, Qi L.M.*, Kinetics-controlled growth of aligned mesocrystalline SnO2 nanorod arrays for lithium ion batteries with superior rate performance, Nano Research, 2013,6(4):243-252 Lin C.F., Lai M.O., Lu L.*, Zhou H.H.*, Xin Y.L., Structure and high rate performance of Ni2+ doped Li4Ti5O12 for lithium ion battery, J. Power Sources, 2013, 244: 272-279. 黄震雷,徐世国,张卫东,杨新河,周恒辉,锂离子电池正极材料产业化进展,新材料产业,2013,10:9-12 Cheng F.Q., Xin Y.L.,Chen J.T., Lu L.*, Zhang X.X., Zhou H.H.*,Monodisperse Li1.2Mn0.6Ni0.2O2 microspheres with enhanced lithium storage capability. J. Mater. Chem. A, 2013,1(17):5301-5308 Tan Z., Wang X.Y.*, Zhou H.H.*, Highly energy density olivine cathode material synthesized by coprecipitation technique. Electrochimica Acta, 2013,90:957-603 Liu W., Gao P., Mi Y.Y., Chen J.T.*, Zhou H.H.*, Zhang X.X., Fabrication of high tap density LiFe0.6Mn0.4PO4/C microspheres by a double carbon coating-spray drying method for high rate lithium ion batteries. J. Mater. Chem. A, 2013, 1(7): 2411-2417. Zhang W.D., Wan W., Zhou H.H.*, Chen J.T., Wang X.Y., Zhang X.X., In-situ synthesis of magnetite/expanded graphite composite material as high rate negative electrode for rechargeable lithium batteries. J. Power Sources, 2013, 223: 119-124. Wang C., Wan W., Chen J.T.*, Zhou H.H., Zhang X.X., Yuan L.X., Huang Y.H.*, Dual core–shell structured sulfur cathode composite synthesized by a one-pot route for lithium sulfur batteries, J. Mater. Chem. A, 2013, 1(1): 1716-1723. Liu W., Wang M., Gao X.L., Zhang W.D., Chen J.T.*, Zhou H.H.*, Xinxiang Zhang. Improvement of the high-temperature, high-voltage cycling performance of LiNi0.5Co0.2Mn0.3O2 cathode with TiO2 coating. Journal of Alloys and Compounds, 2012, 543: 181-188. Zhang W.D., Wang X.Y., Zhou H.H.*, Chen J.T., Zhang X.X., Fe3O4-C open hollow sphere assembled by nanocrystals and its application in lithium ion battery. Journal of Alloys and Compounds, 2012, 521: 39-44. Gao P.,Tan Z., Cheng F.Q., Zhou H.H.*, Tan S.T.*, Effect of Doping with Ti4+ Ion on the Electrochemical Performance of LiFe0.6Mn0.4PO4/C, Acta Phys. Chim. Sin. , 2012, 28(2): 338-342 Wang Z.P., Liu W., Wang Y., Zhao C.S., Zhang S.P., Chen J.T., Zhou H.H., Zhang X.X., Synthesis and characterization of Mg and Ti ions co-doped lithium iron phosphate and its lithium ion batteries, Acta Phys. Chim. Sin. , 2012, 28(9): 2084-2090 Zhao C.L., Li Q., Wan W., Li J.M., Li J.J., Zhou H.H.*, Xu D.S.*. Coaxial carbon-silicon-carbon nanotube arrays in porous anodic aluminum oxide templates as anodes for lithium ion batteries. J. Mater. Chem., 2012, 22(24): 12193-12197. Li J.M., Wan W., Zhu F., Li Q., Zhou H.H., Li J.J., Xu D.S.*. Nanotube-based hierarchical titanate microspheres. an improved anode structure for Li-ion batteries. Chem. Commun., 2012, 48(3): 389-391. 刘文,王苗,陈继涛*,张新祥,周恒辉*,锂离子电池正极材料LiNi0.5Co0.2Mn0.3O2的合成及其高温容量衰减研究,电化学,2012,18(2):118-124 黄震雷, 王峰, 向德波, 郭晓丰, 周恒辉*, 锂离子动力电池三元正极材料的机遇与挑战,新材料产业,2012,9:2-9 Li J.M., Wa W., Zhou H.H.*, Li J.J., Xu D.S.*, Hydrothermal synthesis of TiO2(B) nanowires with ultrahigh surface area and their fast charging and discharging properties in Li-ion batteries, Chem. Commun., 2011, 47: 3439-3441 Ye J.F., Liu W., Cai J.G., Chen S., Zhao X.W., Zhou H.H., Qi L.M.*, Nanoporous Anatase TiO2 Mesocrystals: Additive-Free Synthesis, Remarkable Crystalline-Phase Stability, and Improved Lithium Insertion Behavior,J. Am. Chem. Soc., 2011, 133: 933–940 Cheng F.Q., Wan W., Tan Z., Huang Y.Y., Zhou H.H.*, Chen J.T., Zhang X.X., High power performance of nano-LiFePO4/C cathode material synthesized via lauric acid-assisted solid-state reaction, Electrochimica Acta , 2011, 56:2999-3005 Tan Z., Gao P. , Cheng F.Q. , Luo H.J., Chen J.T. , Zhou H.H.*, Tan S.T., High Power Performance of Multicomponent Olivine Cathode Material for Lithium-ion Batteries, Func. Mater. Lett., 2011,4(3): 299-303 Gu Y.J.,Hu Y.,Liu H.Q.,ZhouH.H.,Guo Z.,Hu Z.W.,Synthesis the Precursor of LiNi0.5Mn0.5O2 via an Improved Carbonate Co-precipitation,Advanced Materials Research, 2011,233-235:32-35 Huang Y.Y., Chen J.T., Cheng F.Q., Wan W., Liu W., Zhou H.H.*, Zhang X.X., A modi?ed Al2O3 coating process to enhance the electrochemical performance of Li(Ni1/3Co1/3Mn1/3)O2 and its comparison with traditional Al2O3 coating process, J. Power Sources, 2010,195: 8267–8274 周恒辉,锂离子动力电池电极材料产业化进展,新材料产业,2010,10:3-5 Huang Y.Y., Chen J.T., Ni J.F., Zhou H.H.*, Zhang X.X.,A modified ZrO2-coating process to improve electrochemical performance of Li(Ni1/3Co1/3Mn1/3)O2, J. Power Sources, 2009, 188(2):538-545 Li C.Q., Sun N.J., Ni J.F., Wang J.Y., Chu H.B., Zhou H.H., Li M.X., Li Y.*, Controllable preparation and properties of composite materials based on ceria nanoparticles and carbon nanotubes, J. Solid State Chem.,2008, 181(10):2620-2625 Ni J.F., Zhou H.H.*, Chen J.T., Zhang X.X.,Improved electrochemical performance of layered LiNi0.4Co0.2Mn0.4O2 via Li2ZrO3 coating,Electrochimica Acta , 2008,53(7): 3075-3083 Qiu J.Y., Zhao L., Zhai M.L.*, Ni J.F., Zhou H.H.*,Peng J., Li J.Q., Wei G.S.,Pre-irradiation grafting of styrene and maleic anhydride onto PVDF membrane and subsequent sulfonation for application in vanadium redox batteries,J. Power Sources, 2008,177: 617–623 Li S.H., Sun N.J., Huang Y.Y., Qin Y., Zhao N.N., Gao J.N., Li M.X., Zhou H.H., Qi L.M.*,Topotactic Transformation of Single-Crystalline Precursor Discs into Disc-Like Bi2S3 Nanorod Networks,Adv. Func.Mater., 2008, 18: 1194–1201 Peng J.F.,Qiu J.Y., Ni J.F., Zhai M.L., Xu P., Zhou H.H., Li J.Q., Wei G.S.,Radiation synthesis and characteristics of PTFE-g-PSSA ion exchange membrane applied in vanadium redox battery, Nucl. Sci. Tech., 2007 , 18 (1) : 50-54 Qiu J.Y., Li M.Y., Ni J.F., Zhai M.L.*, Peng J., Xu L., Zhou H.H.*, Li J.Q., Wei G.S., Preparation of ETFE-based anion exchange membrane to reduce permeability of vanadium ions in vanadium redox battery,J.Membr. Sci., 2007,297 (1-2):174-180 Ni J.F.,Zhou H.H.*,Chen J.T.,Zhang X.X.,Molten salt synthesis and electrochemical properties of spherical LiFePO4 particles,Mater. Lett.,2007,61(3-4):1260~1264 Qiu J.Y., Ni J.F., Zhai M.L., Peng J., Zhou H.H., Li J.Q., Wei G.S.,Radiation grafting of styrene and maleic anhydride onto PTFE membranes and sequent sulfonation for applications of vanadium redox battery, Radia. Phys. Chem., 2007,76 (11-12): 1703-1707 杨 箫, 黄友元,陈继涛,周恒辉*,张新祥,氧化钛包覆对LiCo0.2Ni0.4Mn0.4O2 结构和性能的影响,无机化学学报,2007,23(5):753-758 张淑萍,倪江锋,周恒辉*,张占军*,溶剂热法控制合成规则的LiFePO4 颗粒,物理化学学报,2007,23(6):830-834 Leng Y.H., Li X.G., Yang H.U., Zhou H.H., Prepration and Electrochemical Properties of Nanostructured Li0.8CoO2, International Journal of Nanoscience, 2006, 5(2-3): 285-290 周恒辉*、倪江锋、陈继涛、徐小明、张新祥, LiFePO4的研究及产业化进展,新材料产业,2006,4:49-52 Ni J.F.,Zhou H.H.*,Chen J.T.,Zhang X.X.,LiFePO4 doped with ions prepared by co-precipitation method,Mater. Lett.,2005,59:2361~2365
|